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i will list links below the text
source:
http://autorepair.about.com/library/glossary/bldef-265.htm
pent roof
Definition: A combustion chamber whose upper surface resembles a shallow peaked roof. Usually used with four valves per cylinder.
source:
http://auto.howstuffworks.com/hemi1.htm
In a HEMI engine, the top of the combustion chamber is hemispherical, as seen in the image above. The combustion area in the head is shaped like half of a sphere. An engine like this is said to have "hemispherical heads." In a HEMI head, the spark plug is normally located at the top of the combustion chamber, and the valves open on opposite sides of the combustion chamber.
more from how stuff works
One thing that a hemispherical head will never have is four valves per cylinder. The valve angles would be so crazy that the head would be nearly impossible to design. Having only two valves per cylinder is not an issue in drag racing or NASCAR because racing engines are limited to two valves per cylinder in these categories. But on the street, four slightly smaller valves let an engine breathe easier than two large valves. Modern engines use a pentroof design to accommodate four valves.
hemi history
http://auto.howstuffworks.com/hemi.htm
more history stuff
http://www.allpar.com/mopar/hemi/ardun.html